Search results for "analytical [Methods]"

Electrochemical biosensing using hydrogel nanoparticles

2014

Abstract Biology and medicine have seen great advancements in the development of nanobiosensors capable of characterizing and quantifying biomolecules. This review reports a systematic study of the usefulness of hydrogel nanoparticles (HNPs) in the different steps of the electroanalytical process developed in electrochemical biosensing systems. We illustrate the advantages offered by HNPs in detection of analytes with representative recent examples that highlight the scientific interest in widening the use of HNPs in electrochemical biosensing methods. We review different types of HNP-based electrochemical biosensors, such as enzyme, protein, and nucleic acids, in terms of their sensing per…

A numerical-analytical model for the characterization of composites reinforced by carbon nanotubes

2010

A mixed model, numerical-analytical, is presented that allows one to predict the elastic properties of carbon nanotube (CNT)/polymer composites containing a random distribution of CNTs, while taking account of the curvature that they show when immersed in the polymer. This hybrid approach is a significant advance over micromechanical modeling and can be applied to all nanostructured composites.

Zero- to Ultralow-Field NMR Spectroscopy of Small Biomolecules.

2021

Nuclear magnetic resonance (NMR) spectroscopy is a well-established analytical technique used to study chemicals and their transformations. However, high-field NMR spectroscopy necessitates advanced infrastructure, and even cryogen-free benchtop NMR spectrometers cannot be readily assembled from commercially available components. We demonstrate construction of a portable zero-field NMR spectrometer employing a commercially available magnetometer and investigate its applications in analytical chemistry. In particular, J-spectra of small representative biomolecules [13C]-formic acid, [1-13C]-glycine, [2,3-13C]-fumarate, and [1-13C]-d-glucose were acquired, and an approach relying on the prese…

Computational modeling of molecularly imprinted polymers as a green approach to the development of novel analytical sorbents

2018

Abstract The development of novel molecularly imprinted polymers (MIP) sorbents for specific chemical compounds require a lot of tedious and time-consuming laboratory work. Significant quantities of solvents and reagents are consumed in the course of the verification of appropriate configurations of polymerization reagents. Implementation of molecular modeling in the MIP sorbent development process appears to provide a solution to this problem. Appropriate simulations and computations facilitate the determination of the nature of interaction between the reagents and thus the selection of the best configuration of chemicals for the preparation of the sorbent. The article presents literature …

Time-domain effective-one-body gravitational waveforms for coalescing compact binaries with nonprecessing spins, tides and self-spin effects

2018

We present TEOBResumS, a new effective-one-body (EOB) waveform model for nonprecessing (spin-aligned) and tidally interacting compact binaries.Spin-orbit and spin-spin effects are blended together by making use of the concept of centrifugal EOB radius. The point-mass sector through merger and ringdown is informed by numerical relativity (NR) simulations of binary black holes (BBH) computed with the SpEC and BAM codes. An improved, NR-based phenomenological description of the postmerger waveform is developed.The tidal sector of TEOBResumS describes the dynamics of neutron star binaries up to merger and incorporates a resummed attractive potential motivated by recent advances in the post-Newt…

On the critical velocities and free vibrations of axially moving elastic webs

2014

Toward the Development of Load Transfer Efficiency Evaluation of Rigid Pavements by a Rolling Wheel Deflectometer

2020

The jointed rigid pavement is currently evaluated by the Falling weight deflectometer which is rather slow for the testing of the jointed pavements. Continuous nondestructive evaluation of rigid pavements with a rolling wheel deflectometer can be used to measure the load transfer and is investigated. Load transfer is an important indicator of the rigid pavement&rsquo

Advances in Fourier transform infrared spectroscopy of natural glasses: From sample preparation to data analysis

2014

Fourier transform infrared spectroscopy (FTIR) is an analytical technique utilized to measure the concentrations of H and C species in volcanic glasses. Water and CO2 are the most abundant volatile species in volcanic systems. Water is present in magmas in higher concentrations than CO2 and is also more soluble at lower pressures, and, therefore it is the dominant volatile forming bubbles during volcanic eruptions. Dissolved water affects both phase equilibria and melt physical properties such as density and viscosity, therefore, water is important for understanding magmatic processes. Additionally, quantitative measurements of different volatile species using FTIR can be achieved at high s…

Requirements for using simulation to design and assess wireless ATM handover solutions

1999

Wireless ATM (WATM) has been widely considered as a solution for broadband wireless services. Handover is one of the most important mobility support functions in the WATM network. Many handover solutions have been proposed, analysed, and benchmarked. Simulations have been broadly used to assess these solutions. However, there are many dilemmas in how simulation has been applied as a research methodology: heterogeneous simulation systems used, lack of comparison with other related work, biased conclusions, and unavailability of simulation models and systems to researchers. The WATM research community lacks a standard and commonly acceptable methodology for applying simulation. To address thi…

Failure Load and Collapse Mode of an RC Beam in a Large Collapsed Roof

2021

The present work focused on the determination of the collapse load and of the failure mode of a collapsed framed structure constructed in the South of Italy and failed in 2004 under its self-weight. Information available was the results on extensive experimental test campaign, for the determination of mechanical properties of concrete and steel bars of beams, floors and columns involved in the failure. Moreover, draws of original design with construction details and design rules valid in Italy at the time of construction were found. A simple monodimensional beam model for prediction of load-deflection curve, able to include degradation of constituent materials (concrete, steel and bond) was…